
What is PESU?
Polyethersulfone (PESU) represents a cutting-edge high-performance polymer that has revolutionized advanced manufacturing, particularly in the realm of 3D printing. Unlike conventional thermoplastics, PESU offers a unique combination of mechanical, thermal, and chemical properties that make it exceptionally valuable for complex engineering applications.
At its core, PESU is an amorphous thermoplastic polymer characterized by a sophisticated molecular structure. The polymer features intricate aromatic rings connected by ether and sulfone linkages, which provide its remarkable stability and performance characteristics. This molecular design creates a rigid backbone that enables exceptional thermal resistance and mechanical strength.

History of PESU
Origins of PESU
The journey of PESU began in the late 1960s when materials scientists at leading chemical companies like BASF and Solvay started exploring advanced polymer technologies. Initially developed for aerospace and military applications, PESU represented a breakthrough in high-performance engineering materials.
3D Printing Adaptation
The transition of PESU into 3D printing was a gradual process spanning several decades:
-
1970s-1980s: Initial polymer research and characterization
-
1990s: Early experimental additive manufacturing approaches
-
2000-2010: Advanced material formulation for specialized printing techniques
-
2010-2020: Widespread industrial adoption and technological refinement
Advantages of PESU for 3D Printing
-
Superior Thermal Performance: Maintains structural integrity at high temperatures
-
Exceptional Dimensional Stability: Minimal warpage and deformation
-
Broad Chemical Compatibility: Resistant to numerous chemical environments
-
Lightweight: Provides high strength-to-weight ratio
-
Biocompatibility: Potential medical and healthcare applications
Disadvantages of PESU
Processing Constraints
-
Extremely high processing temperatures
-
Sensitive to moisture absorption
-
Complex printing parameter management
-
Higher material costs compared to standard polymers
Performance Boundaries
-
Potential brittleness under specific mechanical loads
-
Limited color variation
-
Challenging surface finishing requirements
-
Complex post-processing needs
3D Printer Requirements for PESU
To 3D print with PESU (Polyethersulfone), you'll need a 3D printer with specific features to handle its high processing requirements. Here’s a list of key printer requirements for PESU:
Temperature Range: PESU requires a hotend capable of reaching temperatures between 360°C to 400°C (depending on the specific variant of PESU). A standard hotend won’t be sufficient, so you'll need a high-temperature extruder.
Nozzle Material: The nozzle should be made from high-temperature resistant materials like hardened steel or tungsten carbide to avoid wear.
Bed Temperature: A heated bed is essential for preventing warping. Set the bed temperature to around 120°C to 150°C for optimal adhesion of the first layer.
Bed Surface: Use surfaces like PEI or Kapton tape to improve adhesion and minimize warping.
Stable Environment: PESU is prone to warping due to its high printing temperature, so an enclosed print chamber helps maintain a stable, warm environment during printing, reducing the risk of thermal shrinkage.
Speed: Print speeds for PESU are typically slower than standard filaments, around 30-50 mm/s, to ensure better quality and adhesion.
Layer Height: A standard layer height between 0.1 mm to 0.2 mm is ideal for good results.
Reduced Cooling: Minimize the use of part cooling fans, as rapid cooling can cause warping or cracking in PESU. A low or no fan speed is usually recommended.
Dry Storage: PESU is hygroscopic (absorbs moisture from the air), so it should be stored in a dry environment or desiccant bag to avoid printing issues like bubbling or poor layer bonding.
Printer Compatibility
Direct Drive Extruder: A direct drive extruder can provide better filament control, especially for high-temperature filaments like PESU.
High-Temperature Printer: Ensure your 3D printer is rated for high-temperature printing (like those that support PEEK, ULTEM, or PC filaments).
Material Properties of PESU
Bed Temp | 110-150°C |
Density | 1.4 g/cm3 |
Heated Bed | Required |
Coefficient of Thermal Expansion | 5.5 µm/m-°C |
Ultimate Strength | 85 MPa |
Extruder Temp | 340-380°C |
Printability | Difficult |
Max Service Temp | 185°C |
Stiffness | High |
Durability | High |
Designing for PESU
Designing for PESU (Polyethersulfone) in 3D printing requires special considerations to ensure optimal print quality, strength, and durability. Here are key points to keep in mind when designing parts specifically for PESU:
Support Structures: PESU has a high risk of warping, so avoid steep overhangs (angles over 45°) and complex geometries that require excessive support. If overhangs are unavoidable, design in such a way that supports can be easily removed or are minimized.
Gentle Curves: Opt for gradual curves and smooth transitions in your design to help reduce stress during cooling and improve strength.
Print Orientation: Carefully consider the orientation of the part during printing. For instance, parts with a high vertical load should be printed with the build height aligned with the Z-axis to maximize strength.
Warpage Minimization: Position parts so that they don’t excessively cool unevenly. Aligning flat surfaces horizontally can minimize warping.
Thicker Walls: To ensure strength, use thicker walls, generally around 2-4 mm depending on the part's function. Thin walls may lead to failure under stress or impact.
Optimal Layer Height: A layer height of 0.1 mm to 0.2 mm provides a balance between precision and printing speed. Thicker layers might cause adhesion problems, and thinner layers may increase print time without significant quality improvements.
Infill Density: Use 40-60% infill for most parts, depending on the strength needed. Higher infill may be necessary for critical load-bearing parts, but it will also increase print time and material usage.
Infill Pattern: A grid or triangular pattern is usually preferred for strength. It helps with layer bonding and provides better support during cooling.
Detailing: PESU is typically not ideal for extremely fine details or intricate features due to its higher melting temperature and print complexity. Aim for larger features and avoid delicate or thin sections.
Smooth Surfaces: Post-processing is easier when surfaces are designed to be smooth and without significant overhangs. This minimizes the effort required for sanding or other finishing methods.
Threaded Inserts/Features: If incorporating threads or inserts, design them larger than usual, as PESU’s high stiffness can make fine threading challenging.
Allowance for Shrinkage: PESU has a tendency to shrink during cooling. Incorporate tolerances that account for this thermal contraction, especially in high-precision parts, to ensure parts fit properly after printing.
Fit and Tolerances: Allow slightly looser fits to compensate for the minor warping and shrinkage that may occur during cooling.
Thin Sections: Avoid thin, flat sections in your design that may warp or curl during printing. Instead, use thicker sections and consider adding fillets or radii to corners to improve durability.
Support Design: If supports are necessary, make sure they are easy to remove and avoid excessive contact with the part surface. You can design overhangs in such a way that they minimize support usage, or use breakaway supports.
Bridging: For sections that require bridging, ensure that your design includes wider spans and thicker sections that allow for the material to solidify without sagging.
Environmental and Safety Considerations
Hotend and Bed Temperatures: PESU requires high printing temperatures (up to 400°C for the extruder and 150°C for the heated bed). This can pose a safety risk if the printer isn’t properly managed. Always ensure that:
The printer is in a well-ventilated area to dissipate heat.
Hot surfaces should be clearly marked and kept out of reach of children and pets to prevent burns.
Fume Emission: Like many high-temperature thermoplastics, PESU can emit fumes when heated, particularly at higher temperatures. These fumes are not typically considered as toxic as some other high-performance filaments (like ABS), but they still may contain volatile organic compounds (VOCs).
Moisture Sensitivity: PESU is hygroscopic, meaning it absorbs moisture from the air, which can affect print quality and lead to issues like bubbling or inconsistent extrusion. To prevent this, store PESU filament in a dry environment (e.g., in a filament storage box with desiccants). If the filament absorbs moisture, dry it before printing (using an oven or a filament dryer).
Non-Biodegradable Waste: Like many plastic materials, PESU is non-biodegradable and should not be disposed of in regular trash. Dispose of failed prints or waste in appropriate plastic recycling bins that accept high-performance plastics, if available.
Recycling: As with most 3D printing filaments, recycling PESU is not straightforward. Ensure that your local recycling facility can process engineering plastics or check with the filament manufacturer for any guidelines on recycling.
Protective Gear: Given the high temperatures and possible fume emissions, it's recommended to use protective gloves when handling the hotend and heated bed during or after a print.
Eye Protection: It's a good practice to wear safety glasses if you're working in close proximity to the printer, especially if you're sanding or post-processing prints, to protect from potential flying particles or fumes.
Applications of PESU
-
Aerospace & Aviation: Lightweight, heat-resistant parts like connectors and brackets.
-
Automotive: Functional prototypes and durable engine components.
-
Medical: Biocompatible implants, surgical tools, and prosthetics.
-
Electronics: Durable enclosures and insulating components.
-
Industrial & Engineering: Custom tools, fixtures, and parts for harsh environments.
-
Consumer Goods: Durable household items like kitchen tools and appliance parts.
-
Defense & Military: Strong, heat-resistant parts for military equipment.
-
Robotics: Tough components like robot arms and structural elements.
-
Energy & Utilities: Heat-resistant parts for power plants and renewable energy systems.
PESU’s heat, chemical resistance, and strength make it ideal for these diverse, high-performance applications.
Not right for you? Learn about other materials here.
